مشخصات جذب سطحی کادمیم در تعدادی از خاک‌های آهکی ایران

نوع مقاله : مقاله پژوهشی

نویسندگان

1 دانشجوی کارشناسی ارشد دانشگاه آزاد اسلامی واحد کرج

2 استادیار پژوهش موسسه تحقیقات خاک و آب

چکیده

زیست فراهمی و سرنوشت نهایی فلزات سنگین در محیط زیست بوسیله جذب شیمیایی کنترل می­گردد. در این پژوهش، خصوصیات جذب کادمیم در 19 خاک آهکی ایران در دامنه­ای از غلظت کادمیم (mM Cd8/12 – 024/0) و دمای 25 درجه سانتیگراد مطالعه گردید. همدماهای جذب بخوبی توسط معادلات فروندلیچ و لانگمویر توضیح داده شدند (00/1-95/0R2=  و 99/0-94/0R2= به ترتیب برای معادله­های لانگمویر و فروندلیچ). پارامتر حداکثر جذب کادمیم (qm) محدوده­ی بین 2460 تا 10226 میلی­گرم بر کیلو­گرم داشت. خاک­های با رس بالا بر اساس پارامتر حداکثر جذب لانگمویر بیشترین ظرفیت جذب را داشتند. نتایج نشان داد که رس، شن، کربن­آلی و ظرفیت تبادل­کاتیونی مهم­ترین خصوصیاتی از خاک هستندکه جذب کادمیم در خاک­های آهکی را تحت تأثیر قرار می­دهند. پارامتر حداکثر جذب لانگمویر و ضریب فروندلیچ همبستگی معنی­داری با ظرفیت تبادل کاتیونی، رس، سیلت، کربن آلی و شن داشتند. همچنین نتایج این مطالعه نشان داد که مقدار کربنات کلسیم معادل (CCE) با هیچ­کدام از پارامترهای معادلات همدمای جذب همبستگی معنی­داری ندارد.

کلیدواژه‌ها

عنوان مقاله [English]

Adsorption Characteristics of Cadmium by Some Calcareous Soils of Iran

نویسندگان [English]

  • Sh. Sharafbafi 1
  • K. Shahbazi 2
1 .Sc Student of Soil Science Department, faculty of Agriculture, Islamic Azad University of Karaj
2 Assistant Professor, Soil and Water Research Institute
چکیده [English]

The bioavailability and ultimate fate of heavy metals in the environment are controlled by chemical sorption. In this study, sorption characteristics of Cd in 19 calcareous soils of Iran were assessed at varying Cd concentrations (0.024-12.8 mM Cd) and 25°C. Sorption isotherms were well described by the Langmuir and Freundlich equations (R2= 0.95-1.00 and R2= 0.94-0.99 for Langmuir and Freundlich models, respectively).The maximum adsorption capacity of soils ranged from 2460 to 10226 mg kg-1. Soils with higher clay content had greatest sorption capacity as estimated by the maximum sorption parameter of the Langmuir equation. The results revealed that cation exchange capacity (CEC), clay, sand, and OC were the most important soil properties affecting Cd adsorption behavior in calcareous soils. Maximum adsorption parameter of Langmuir and Freundlich constant coefficients were significantly correlated with clay, sand, silt, CEC, and OC. However, No statistically significant relation was found between the model parameters and calcium carbonate equivalent (CCE)

کلیدواژه‌ها [English]

  • Adsorption isotherm
  • Langmuir and Freundlich models

مراجع

  1. Adhikari, T., and M.V. Singh. 2003. Sorption characteristics of lead and cadmium in some soils of India. Geoderma 114: 81-92.
  2. Agbenin, J.O., L.A. Olojo. 2004. Competitive adsorption of copper and zinc by a Bt horizon of a savanna Alfisol as affected by pH and selective removal of hydrous oxides and organic matter. Geoderma 119:85–95.
  3. Ainsworth, C.C., J.L. Pilon, P.L.  Gassman, and W.G. Vandersluys. 1994. Cobalt, cadmium, and lead sorption to hydrous iron oxide: residence time effect. Soil Sci. Soc. Am. J. 58:1615–1623.
  4. Alamino, R., H. Polivanov, and E.V. Barroso. 2009. Comparative effect of the sorption of cadmium in organic and kaolinitic soils. Culshaw, m. G., H. J. Reeves, I. Jefferson, and T. W. Spink,(eds), Engineering geology for tomorrow's cities, Geological Society, London, Engineering geology apecial publication, 22[on CD-ROM insert, paper 347].
  5. Allison, L.E. and C.D. Moodi. 1962. Carbonates. PP 1379-1396. In: C. A. Black et al. (ed), Methods of Soil Analysis. Part 2, Am. Soc. Agron., Madison,WI.
  6. Appel,  C.,  and  L. Ma.  2002.  Concentration,  pH,  and  surface  charge  effects  on cadmium and  lead sorption  in  three tropical soils. J. Environ. Qual. 31: 581-589.
  7. Arias, M., C. Perez-Novo, F. Osori, E. Lopez, B. Soto. 2005. Sorption and desorption of copper and zinc in the surface layer on acid soils. J. Colloid Interface Sci. 28: 21–29.
  8. Barkat, M., D. Nibou, S. Chearouche, and A. Mellah. 2009. Kinetics and thermodynamics studies of  chromium(VI) ions adsorption onto activated carbon from aqueous solutions. Chem. Eng. Process. 48: 38–47.
  9. Basta, N.T., and M.A. Tabatabai. 1992. Effect of cropping systems on adsorption of metal by soils 1. Single metal adsorption. Soil Sci. 153: 108–114.
  10. Basta, N.T., and M.A.Tabatabai. 1992a. Effect of cropping systems on sorption of metals by soils: III. Competitive sorption. Soil Sci. 153: 331–337.
  11. Biswas, K., S.K. Saha, and U.C. Ghosh. 2007. Adsorption of fluoride from aqueous solution by a synthetic iron(III)–aluminum(III) mixed oxide, Ind. Eng. Chem. Res. 46: 5346–5356.
  12. Bolton, K.A., and L.J. Evans. 1996. Cadmium adsorption capacity of elected Ontario soils. Can. J. Soil Sci. 76: 183–189.
  13. Boparai, H.K., M.A. Joseph, and D. O’Carroll. 2010. Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles. J. Hazard. Mater.186: 458-465.
  14. Bouyoucos, G.J. 1962. Hydrometer method improved for making particle size analysis of soils. Agron. J. 54: 464-465.
  15. Bru¨mmer,  G.W., J. Gerth , and U. Herms. 1986. Heavy metal species, mobility, and availability in soils. Zeitschrift fu ¨r Pflanzenerna ¨hrung und Bodenkunde. 149:382–398.
  16. Bru ¨mmer, G.W., J. GerthJ, and K.G. Tiller. 1988. Reaction kinetics of the adsorption and desorption of nickel, zinc and cadmium by goethite. I.Adsorption and diffusion of metals. J. Soil Sci. 39:37–5.
  17. Buchter, B., B. Davidoff, M.C. Amacher, C. Hitz, I.K. Eskander, and H.M. Selim. 1998. Correlation of Freundlich Kd and N retention parameters with soils and elements. Soil Sci.  148: 370–379.
  18. Cavallaro,  N.,  and  M.B. McBride.  1978.  Copper  and  cadmium  adsorption  characteristics  of  selected  acid  and  calcareous  soils. Soil Sci. Soc. Am. J. 42: 550-556.
  19. Chapman, H.D. 1965. Cation exchange capacity. P.891-902.In C. A. Black et al. (ed). Methods of soil analysis, part 2, ASA, Madison,WI.
  20. Chen, X., J.V. Wrigth, J.L. Conca, and L.M. Peurrung. 1997. Effects of pH on heavy metal sorption on mineral apatite. Environ. Sci. Technol. 31:624–631.
  21. Chingombe, P., B. Saha, and R.J. Wakeman. 2006. Sorption of atrazine on conventional and surfacemodified activated carbons. J. Colloid Interface Sci. 302 : 408–416.
  22. Elebi, O.C.¸ C. Uzum, T. Shahwan, and H.N. Erten. 2007.  A radiotracer study of the adsorption behavior of aqueous Ba2+ ions on nanoparticles of zero-valent iron. J. Hazard. Mater. 148 : 761–767.
  23. Ellis, S.R., M.E. Hodson, and P. Wege. 2006. The influence of different artificial soil types on the acute toxicity of carbendazim to the earthworm Eisenia fetida in laboratorytoxicity tests. 8th International Symposium on Earthworm Ecology (ISEE8),Cracow, POLAND.
  24. Esfandbod, M., A. Forghani, E. Adhami, and M. Rashti .2010. Cadmium adsorption behavior of some soils from northern of Iran.19th   World Congress of Soil Science, Brisbane, Australia.
  25. Essington, M.E. 2003. Soil and water chemistry: An integrative approach. CRC Press, Boca Raton, FL.
  26. Gerritse, R.G., and W. Vandriel. 1984. The relationship between adsorption of trace metals, organic matter, and pH in temperate soils. J. Environ. Qual. 13:197–204.
  27. Gomes, P.C., M.P.F. Fontes, A.G. Da Silva, E.S.Mendonça, and R.A. Netto. 2001. Selectivity sequence and competitive sorption of heavy metals by Brazilian soils. Soil Sci. Soc.Am. J. 65:1115–1112.
  28. Gray, C.W., R.G. McLaren, A.H.C. Roberts, and L.M. Condorn. 1998. Sorption and desorption of cadmium from some New Zealand soils: Effect of pH and contact time. Aust. J. Soil Res. 36: 199-216.
  29. Hanafi, M.M., and J. Sjiaola. 1998. Cadmium and zinc in acid tropical soils. 1. Soil physicochemical properties effect on their adsorption. Commun. Soil Sci. Plant Anal.  29: 1919–1931.
  30. Harter, R.D., and R. Naidu. 1995. Role of metal-organic complexation in metal sorption by soils. Adv. Agron. 55:219–263.
  31. Helweg, A., 1977. Degradation and adsroption of carbendazimand 2-aminobenzimidazole in soil. Pesticide Science 8:71–78.
  32. Hirsch, D., and A. Banin. 1990. Cadmium speciation in soil solution. J. Environ. Qual. 19:366–372.
  33. Holm, P.E., B.B.H. Andersen, and T.H. Christensen. 1996. Cadmium solubility in aerobic soils. Soil Sci. Soc. Am. J. 60: 775–780.
  34. Holm, P.E., H. Rootzn, O.K. Borggaard, J.P. Moberg, and T.H. Christensen. 2003. Correlation of cadmium distribution coefficients to soil characteristics. J. Environ. Qual. 32:138–145.
  35. Hondal H.S., R. Kumar, K. Singh , and D. Singh. 2005. Cadmium sorption by some alkaline soils of North-West India. American Institute of chemical Engineers, Annual metting.2881.
  36. Hooda, P.S., and B.J. Alloway. 1994. Sorption of Cd and Pb by selected temperate and semi-arid soils: effects of sludge application and ageing of sludge soils.Water Air Soil Pollut. 74: 235–250.
  37. Jalali, M., S. Moharrami. 2007. Competitive adsorption of trace elements in calcareous soils of western Iran. Geoderma. 140 :156–163
  38. John, M.K., 1971. Cadmium adsorption maxima of soils as measured by the Langmuir isotherm. Can. J. Soil Sci.52:343-350.
  39. Kabata-Pendias, A. and H. Pendias. 1992. Trace elements  in soils and plants. 3rd ed. CRC. Press: Boca Raton, London, New York, Washington, D. C.
  40. Liao, L., and H.M. Selim. 2009. Competitive Sorption of Nickel and Cadmium in Different Soils. Soil Sci.174:549-555.
  41. Maftoun,  M.,  F.  Rassooli,  Z.  Ali  Nejad,  and  N.  Karimian.  2004.  Cadmium sorption  behavior  in  some  highly  calcareous  soils  of  Iran. Communications in Soil Science and Plant Analysis 35:1271-1282.
  42. McBride. M.B., C.E. Martinez, E. Topp,  and L. Evanis. 2000. Trace metal solubility and speciation in a calcareous soil 18 years no-till sludge application. Soil Sci. 165: 646-656.
  43. McLaren, R.G., C.A. Backes , A.W. Rate , R.S. Swift. 1998. Cadmium and cobalt desorption kinetics from soil clays: Effect of sorption period. Soil Sci. Soc. Am. J. 62:332–337.
  44. McLaren, R.G., D.S. Hogg, and R.S. Swift. 1990. Some factors affecting the availability of native and applied soil copper in NewZealand soils. For. Ecol.Manage. 37: 131–142.
  45. McLean, J.E.,  and  B.E. Bledsoe. 1992. Behaviour of metals in soils. EPA/540/S-92/018. 25p.
  46. Moral, R.,  J. Moreno-Caselles, M. Perez-Murcia, and A. Perez-Espinosa. 2002. Improving  the  micronutrient  availability  in  calcareous  soils  by  sewage sludge  amendment. Commun. Soil Sci. Plant Anal. 33: 3015-3022.
  47. Naidu, R.,  R.S. Kookana, M.E. Sumner,  R.D. Harter, K.G.Tiller.1997. Cadmium sorption and transport in variable charge soils: areview. J. Environ. Qual. 26: 602–617.
  48. Naidu, R., M.E. Sumner, and R.D. Harter. 1998.Sorption of heavy metals in strongly weathered soils: an overview. Environ. Geochem. Health. 20:5–9.
  49. Nelson, D.W., and L.E. Sommer. 1982. Total carbon, organic carbon, and organic matter. p.539-579. In A.L. Page (ed.) Methods of Soil Analysis. 2nd Ed. ASA Monogr. 9(2). Amer. Soc.Agron. Madison, WI.
  50. Papini, M.P., T. Saurini, and A. Bianchi. 2004. Modeling the competitive adsorption of Pb, Cu, Cd and Ni onto a natural heterogeneous sorbent material (Italian BRed Soil[). Ind. Eng. Chen. Res. 43:5032-5041.
  51. Rhoades, J.D. 1996. Salinity: electrical conductivity and total dissolved solids. In: D. L. Sparks, (ed.), Methods of Soil Analysis. Part 3, chemical methods. SSSA, Madison, WI.
  52. Romkens, P., J. Dolfing.1998. Effect of Ca on the solubility and molecular size distribution of DOC and Cu binding in soil solution samples. Environ. Sci. Technol. 32:363–369
  53. Safarzadeh, S., A. Roghani, and  N. Karimian. 2009. Comparison of Cadmium Adsorption Behavior in Selected Calcareous and Acid Soils. Iran Agricultural Research, Vol. 29:63-75.
  54. Serranoa, S., F. Garrido, C.G. Campbell  , M.T. Garcı -Gonzalez. 2005. Competitive sorption of cadmium and lead in acid soils of Central Spain. Geoderma 124 : 91–104.
  55. Shaheen, S. M., 2009. Sorption and lability of cadmium and lead in different soils from Egypt and Greece. Geoderma 153 : 61–68.
  56. Sheindorf, C., M. Rebhun, and M. Sheintuch. 1981. A Freundlich-type multicomponent isotherm. J. Colloid Interface Sci. 79:136-142.
  57. Silveira, M.L.A., L.R.F. Alleoni, and L.R.G. Guilherme. 2003. Review: Biosolids and heavy metals in soils. Scientia Agricola, 60: 793-806.
  58. Silveira, M.L.A., L.R.F. Alleoni, O.A. Camargo, and J.C. Casagrande. 2002. Copper adsorption in oxidic soils after removal of organic matter and iron oxides. Commun.  Soil Sci. Plant Anal. 33:3581–3592
  59. Singh, S.P., L.Q. Ma,  and W.G. Harris. 2001. Heavy metal  interactions with phosphatic  clay:  Sorption  and  desorption  behavior.  J.  Environ. Qual. 30: 1961–1968.
  60. Singh, S.P., V.K. Nayyar.1993. Adsorption of cadmium on alkaline and calcareous soils. Indian J. Soil Sci. Soc. 41: 270–273.
  61. Sparks, D.L., 1995. Environmental Soil Chemistry. Academic Press, New York.
  62. Sposito, G. 1980. Derivation of the Freundlich equation for ion exchange in soils. Soil Sci. Soc. Am. J. 44: 652–654.
  63. Sposito, G. 1984. The Surface Chemistry of Soils. Oxford University Press, New York, NY.
  64. Sposito, G. 1989. The Chemistry of Soils. Oxford University Press, New York.
  65. Tan, G.Q.,  D. Xiao. 2009. Adsorption of cadmiumion fromaqueous solution by ground wheat stems. J. Hazard. Mater. 164: 1359–1363.
  66. U.S. Salinity Laboratory Staff.1954. Diagnosis and improvement of saline and alkali soils. U.S. Dep. Of Agriculture Handbook no. 60, U.S. Government Printing Office, Washington, DC.
  67. Usman, A.R.A. 2008. The relative sorption selectivities of Pb, Cu, Zn, Cd and Ni by soils developed on shale in New Valley, Egypt. Geoderma 144: 334–343.
  68. Vigil, D.L.V., M.D. Flor, and V.Cala.1997. Influence of carbonate on cadmium distribution in soils under semiarid environment. Agrochimica. 41:270–278.
  69. Virag, D., and A. Kiss. 2009. Comparative study of accessibility of distinctive pesticides. Journal of Environmental Science and Health. Part B: Pesticides, Food Contami-nants, and Agricultural Wastes 44: 69–75.
  70. Wan Zuhairi, W.Y., and S. Abdul Rahim. 2007. Sorption parameters of Pb and Cu  on  natural  clay  soils  from  Selangor, Malaysia.  Sains Malaysiana  36(2): 149-157. 
  71. Wang, Y.J., D.M. Zhou, X.S.  Luo, R.J. Sun, and H.M. Chen. 2004. Cadmium adsorption in montmorillonite  as affected by glyphosate. J. Environ. Sci.China 16: 881–884.
  72. Wong, J.W.C., K.L. Li, L.X. Zhou, and A. Selvam. 2007. The sorption of Cd and  Zn  by  different  soils  in  the  presence  of  dissolved  organic matter  from sludge. Geoderma 137: 310–317.
  73. Yang , C.H. 1998. Statistical mechanical study on the Freundlich isotherm equation. J. Colloid Interface Sci. 208 : 379–387.
  74. Yuan,  G.,  and  L. M.  Lavkulich.  1997.  Sorption  behavior  of  copper,  zinc,  and cadmium  in  response  to  simulated  changes  in  soil  properties. Commun. Soil Sci. Plant Anal. 28: 571-587.
پژوهش های خاک
دوره 28، شماره 1
شهریور 1393
صفحه 65-76

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